Available on-demand - *F.EL07.02.07
Enlightening Polymer Electronic Devices
Paolo Samori1
University of Strasbourg1
Show Abstract
The development of multifunctional devices capable to respond to multiple and independent stimuli is one among the grand challenges in organic electronics. The combination of multiple components, with each one conferring a specific function to the ensemble, is a facile strategy to impart a multifunctional nature to electronic devices. The controlled combination of such components and their integration in real devices can be achieved by mastering the supramolecular approach.
In my lecture I will review our recent works on the combination of carbon-based nanomaterials, in particular comprising organic semiconductors, with photochromic molecules (diarylethenes or azobenzenes) in order to fabricate smart, high-performing and light-sensitive (opto)electronic devices such as field-effect transistors and light-emitting transistors and as well as flexible non-volatile optical memory thin-film transistor device with over 256 distinct levels.
References
[1] For reviews see: (a) X. Zhang, L. Hou, P. Samorì, Nat. Commun. 2016, 7, 11118. (b) E. Orgiu, P. Samorì, Adv. Mater. 2014, 26, 1827-1845.
[2] For modulating charge injection at metal-organic interface with a chemisorbed photochromic SAM see: (a) N. Crivillers, E. Orgiu, F. Reinders, M. Mayor, P. Samorì, Adv. Mater. 2011, 23, 1447-1452. (b) T. Mosciatti, M.G. del Rosso, M. Herder, J. Frisch, N. Koch, S. Hecht, E. Orgiu, P. Samorì, Adv. Mater. 2016, 28, 6606.
[3] For hybrid structure combining organic semiconductors blended with Au nanoparticles coated with a photochromic SAM see: C. Raimondo, N. Crivillers, F. Reinders, F. Sander, M. Mayor, P. Samorì, Proc. Natl. Acad. Sci. U.S.A. 2012, 109, 12375-12380.
[4] For blends energy level phototuning in a photochromic - organic semiconductor blend see: (a) E. Orgiu, N. Crivillers, M. Herder, L. Grubert, M. Pätzel, J. Frisch, E. Pavlica, G. Bratina, N. Koch, S. Hecht, and P. Samorì, Nat. Chem. 2012, 4, 675-679. (b) M. El Gemayel, K. Börjesson, M. Herder, D.T. Duong, J.A. Hutchison, C. Ruzié, G. Schweicher, A. Salleo, Y. Geerts, S. Hecht, E. Orgiu, P. Samorì, Nat. Commun. 2015, 6, 6330.
[5] For the fabrication of memory devices: T. Leydecker, M. Herder, E. Pavlica, G. Bratina, S. Hecht, E. Orgiu, P. Samorì, Nat. Nanotech. 2016, 11, 769–775.
[6] For the novel nanomesh scaffold based photodetector: (a) L. Zhang, X. Zhong, E. Pavlica, S. Li, A. Klekachev, G. Bratina, T.W. Ebbesen, E. Orgiu, P. Samorì, Nat. Nanotech. 2016, 11, 900–906. (b) L. Zhang, N. Pasthukova, Y. Yao, X. Zhong, E. Pavlica, G. Bratina, E. Orgiu, P. Samorì, Adv. Mater. 2018, 30, 1801181.
[7] For optically switchable light-emitting trasnsistors: L. Hou, X. Zhang, G. F. Cotella, G. Carnicella, M. Herder, B. M. Schmidt, M. Pätzel, S. Hecht, F. Cacialli, P. Samorì, Nat. Nanotechnol., 2019, 14, 347–353.